Геохімія важких металів у грунтових відкладеннях зони впливу підприємств кольорової металургї

О. В. Яковенко

Анотація


GEOCHEMISTRY OF HEAVY METALS IN SOILS OF THE ZONE OF INFLUENCE OF THE NONFERROUS METALLURGY ENTERPRISES

A. V. Yakovenko

 

Studying of the total maintenance and forms of heavy metals in soils is the

actual task. It is important as soils as national property play extremely important role in the future development ofUkraine.

Objects of research had been selected soils in an influence zone The nonferrous

metallurgy enterprises (factory "UkrZinc", Konstantinovka Donetsk area). Also for an estimation of degree of pollution and comparison of negative influence of the enterprise reserve soils «Homutovsky step» have been investigated.

In a zone of researches soil adjournment are presented by chornozem with the average maintenance of organic.

As a result of researches it is defined that physical and chemical characteristics

of soils of a zone of influence of industrial complex and background territories cardinally differ. So, the sum absorbed cations ΣΕ it is considerable above in reserve soils. In the polluted soils the maintenance of Corg and Ca+ above in 10 and 4 times accordingly.

By means of a method of phasic extracts forms of a finding of heavy metals

in soils of the mentioned territories are defined.

It is established that the maintenance of the mobile form of Cadmium makes

16 %, Zinc - 16,1 %, Copper - 14 %. It specifies in the raised migratory ability of these elements. The maintenance of mobile forms in the polluted soils considerably above than in conditionally pure.

As a result of geochemical studying of territory the total maintenance of

heavy metals in soils is defined, danger and concentration factors, an indicator of total pollution of territory are calculated. The average maintenance of heavy metals in a zone of influence of industrial complex exceeds background value and maximum permissible concentration in thousand times.

On concentration factor it is allocated geochemical association:
Cd (1,7•104)>> Pb (203)> Zn (53)> Mn.

On a total indicator of pollution ZC the territory of researches is defined by a

zone of ecological accident.


Повний текст:

PDF

Посилання


References

On border of ecological accident. Available at: http//universum.lviv.ua/previous-site/journal/2010/2ecol3.htm

Chunjie, C. Distribution and pollution of soil heavy metals upland around Pindingshan coal mining area / C. Chunjie, Z. Jinfeng // Geographical Research. 2014. – 33 (7). – Р.: 1383 – 1392.;

Bixiong, Y. (2013). Heavy metal pollution and migration in soil-wheay system of different livestock manures agricultural areas / Geographical Research. – 32 (4). – Р:645–652.

Distribution Pattern of Some Heavy Metals in the Soil of Silghat Region of Assam (India), Influenced by Jute Mill Solid Waste/ Pronil Kumar Bora et al. // J. of Chemistry. – 2013. – Vol.7. – Р.812–820.

Zhu, Gang (2012).Combined pollution of heavy metals and PAHs and its risk assessment in industrial sites of Chenzhou city // Geographical Research. – 31(5). – Р. 831-839;

Ji W. The advances in research on heavy metals of the surface dust in urban areas / W. Ji, Zh. Yi-xiu, G.Xiang // Geographical Research. – 2012. – N 31(5). – P.821–830.

Fang Feng-man, Jiang Bing-yan, Wang Hai-dong, Xie Hong-fang / Particle size distribution and health risk assessment of heavy metals in surface dust of Wuhu urban area / Geographical Research. – 2010. – N 29(7). – P. 1193 – 1202.

Distribution of Forms of Heavy Metals in Soils Contaminated by Metallurgical Smelter Emissions Available at: www.pubfacts.com/detail/15055927/Distribution-of-forms-of-heavy-metals-in-soils-contaminated-by-metallurgical-smelter-emissions

Multiple Exposure And Effects assessment of Heavy Metals in the Population near Mining Area in South China. Available at: www.ncbi.nlm.nih.gov/pmc/articles/PMC3984172/

Fraction distribution and risk assessment of heavy metals in stream sediments from a typical nonferrous metals mining city. Available at: www.ncbi.nlm.nih.gov/m/pubmed/23745416/

Baran, A., Chemical properties and toxicity of soils contaminated by mining activity / A. Baran, T.Czech, J.Wieczorek // Ecotoxicology. – 2014. – N 23 (7). – Р.1234 – 1244.

Zhang, X. (2013). The Influence of soil solution properties on phytotoxicity of soil soluble copper in a wide range of soils // Geoderma. – N2. – P. 112 – 211.

Plaza, G. (2010). Ecotoxicological and microbiological characterization of soils from heavy metal and hydrocarbon contaminated sites // Environmental Monitoring and Assessment. – 163. – Р.477 – 488.

Dynamical variation and improvement strategies of urban agricultural development at the country level / D.Wang [et al.] // Geographical Research. – 2014, – Vol.33. - N9. – P. 1706–1715

Ladonin, D.V. (2002). Soedineniya tyazhelyh metallov v pochvah-problemy i metodyizucheniya [Compounds of heavy metals in soils]. Soil Science, 6, 682-692.

Ladonin D.V. (1995). Vliyanie tehnogennoho zagryaznenia na frakzionnyi sostav medi I zinka v pochvah [Influence of technogenic pollution on fractional structure of copper and zinc in soils]. Soil Science, 10, 1299 – 1305.

Samchuk, A.I. Phisiko-himicheskie usloviya obrazovania form toksichnyh metallov [Physic and chemical conditions of forms of toxic metals] / A.I. Samchuk, G.N. Bondarenko, V.V. Dolin, Y.Y. Suschyk, I.F. Shramenko, B.F. Mizkevych, O.S. Egorov// Mineral mag. – 1998. – N 2. – P. 48 – 59.

Zhovinsky, E.Y., Kuraeva I.V. (2002). Geohimia tehnohennyh metallov v pochvah Ukrainy [Geochemistry of technogenic metals in soils of Ukraine]. Kiev, Ukraine: Naukova Dumka, 215.

Kuraeva I.V., Samchuk A.I., Stadnik V.O., Batievsky B.O. (2008). Ecologo-gidrogeohimichni doslidzhennya pryrodnyh vod Kyivs’koho megapolisu [Ecological and gydrogeochemical investigations of nature waters of Kiev-city]. Kiev, Ukraine: IGMOF, 108.

Zhovinsky, E.Y., Keraeva I.V. ed. (2012). Ecologo-geohimichni doslidzhennya obyectiv dovkillia Ukrainy [Ecological and geochemical studies of object of environment of Ukraine]. Kiev, Ukraine: Alpha Reklama, 156.

Ponomarenko, O.M. Analytychni shemi probopidhotovky hirs’kyh porid ta mineraliv I vyznachenya v nyh mikroelementiv metodom mass-spectroskopii z indukzino zvyazanoyu plazmoyu [Analytical sample preparation scheme of rocks and minerals and trace elements determination in them by mass spectrometry with inductively coupled plasma] / O.M.Ponomarenko, A.I.Samchuk, O.P.Krasyuk, T.I.Makarenko, O.G.Antonenko // Mineral mag.– P.97 – 103.

Kuznezov, V.A. Metod stadinyh vytiazhek pri geohimicheskih issledovaniah [Stepwise method of extraction in geochemical studies] / V.A. Kuznezov, G.A. Shimko. – M.: Science and technology, 1990. – 65 p.

Saet, Y.E. Geohimia okruzhayushchey sredi [Environmental Geochemistry] / Y.E. Saet, B.A. Revich. – M.: Nedra, 1990. – 335 p.

Androsova, N.K. (2000). Geologo-ecologicheskie issledovaniya I kartographirovanie [Geological and Environmental studies and mapping] / N.K. Androsova. – M.: RUDN, 98.

Gursky, D.S., Iesypchuk, K.Y., Kalinin, V.I. Metalichni korysni kopalyny [Metallic Minerals]. (2006). Lviv, Ukraine: Center of Europe, 740.

Yakovenko, A.V. (2011). Formy znahodzhennya ta migracii cadmiyu u gruntah ta gruntovych rozchynach tehnogenno zabrudnenych teritorii na prykladi Pobuzkoho feronikelevoho kombinatu [Forms and migration of Cadmium in soil and soil solution technologically contaminated areas for example Pobuzke ferronickel plant] // Zb. nauk. prac’UkrNDMI NAN Ukraine. – - P.416 – 428.


Метрики статей

Завантаження метрик ...

Metrics powered by PLOS ALM

Посилання

  • Поки немає зовнішніх посилань.


Bookmark and Share