Physics and chemical features of the vanadium sulfamate soluble, manganese, chromium and other metals sulfamates

Authors

  • V. Maksin National University of Life and Environmental Sciences of Ukraine image/svg+xml
  • O. Standrytchuk National University of Life and Environmental Sciences of Ukraine image/svg+xml
  • O. Lytovchenko NP NUBiP of Ukraine "Nizhyn Agrotechnical College" , Ніжинський агротехнічний коледж

DOI:

https://doi.org/10.31548/bio2019.05.013

Keywords:

sulfamic acid, sulfamates, solubility of sulfamates, Gibbs energy, sulfamate ion, zwitterionic structure of sulfamate ion, ion radius

Abstract

Dependence of sulfamic acid salts solvability in  water - СS (in  gr of salt/100 gr Н2O) with the general chemical formula Ме(SO3NH2)n, where, Mе+n is one-, two- and three-charge cations of metal, and - n is value of charge, was researched. Also specific aspects of distribution of salts Ме(SO3NH2)n according to calculated size of  Gibbs free energy – ∆GS, from the radius length – r+n(in nm) of  sulfamate formative metal cation were examined.     

      Using graphic methods and methods of mathematical analysis of the functions СS=f(r+n) and ∆GS=f(r+n) correlation of special points of these functions with fundamental physical and chemical constants was found. It was calculated the size of sulfamate-ions radius with cvitter-ion (r-і)+H2NSO3- = 254,932 ± 0,001 pm, and with  open (r-і)NH2SO3- = 255,965 ± 0,005 pm structure. Also estimated values of СS for sulfamates formed by two- and three-charge cations of  Vanadium, Manganese and Chromium were clarified.

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Published

2019-12-20

Issue

Vol. 11 No. 5-6 (2019)

Section

Chemistry

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