Trace analysis of phosphate content in marine waters, sea salts, serum using solid-phase spectrophotometry and visual test technique

Authors

  • О. А. Zaporozhets Taras Shevchenko National University of Kyiv image/svg+xml
  • L. S. Zinko Taras Shevchenko National University of Kyiv image/svg+xml
  • H. S. Sumarokova Taras Shevchenko National University of Kyiv image/svg+xml
  • Yu. S. Prokapalo Taras Shevchenko National University of Kyiv image/svg+xml

DOI:

https://doi.org/10.31548/bio2016.01.006

Abstract

The interaction between reduced molybdo-antimono- phosphoric heteropoly acid and cetyltrimethylammonium bromide adsorbed on to mesoporous silica (CTAB-SG) was studied using adsorption and spectoscopic techniques. It is shown that the adsorption of the heteropoly acid from 0,3 M sulfuric acid solution gives the isotherm of H2-type, the sorption equilibrium is reached in 2 min. Taking this into account, the methods for orthophosphate determination in marine waters and serum were developed. The limits of detection were 0,063 and 0,450 mg/L respectively. Color scales for semiquantitative visual test determination of orthophosphate in the range of 0,03-0,8 and 0,6-1,9 mg/L were proposed too.

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Published

2017-05-11

Issue

Vol. 8 No. 1-2 (2016)

Section

Chemistry

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