Reactivity quinolylhydrazones by reaction with diphenylpicrylhydrazyl

Authors

  • О. І. Khyzhan National University of Life and Environmental Sciences of Ukraine image/svg+xml
  • О. І. Khyzhan , Інститут фізико-органічної хімії і вуглехімії ім. Л.М. Литвиненка НАН України
  • H. A. Tykhonova Donetsk National University ,

DOI:

https://doi.org/10.31548/bio2016.01.007

Abstract

Antiradical activity of quinolylhydrazones in reaction with diphenylpicrylhydrazyl were studied by spectrophotometric method. The kinetic parameters of the reaction were determinated, the effect of solvent on the reactivity of the compounds in the reaction with the radical was studied. Hydrazones antiradical activity towards diphenylpicrylhydrazyl correlates with the activity of these compounds in the reaction with peroxyl radicals.

References

Denisov E., Afanas'ev I. Oxidation and Antioxidants in Organic Chemistry and Biology. Boca Raton, FL: Taylor & Francis, 2005. 992 p.

Маслова В.Ю., Ніколаєвський А.М., Хижан Олена І., Тихонова Г.А., Хижан Олександр І. Антиоксидантна активність хінолілгідразонів при окисненні органічних речовин // Вісник

Донецького національного університету. Сер. А: Природничі науки. - 2014. - № 1. ¬- С.163-165.

Хижан Е.. Кинетика и механизм ингибирующего действия арилгидразонов при жидкофазном окислении органических веществ: Дис. … канд. хим.наук. - Донецк, 2002. -152 с.

Бучаченко А. Л., Вассерман А. М. Стабильные радикалы. Электронное строение, реакционная способность и применение. - М.: Химия, 1973.- 408 с.

Barclay Z.R.C., Edwards C.E., Vingvist M.R. Media Effect on Antioxidant Activities of Phenols and Catechols // J. Amer. Chem. Soc. - 1999. - 121, № 26. - P. 6226-6231.

https://doi.org/10.1021/ja990878u

Волков В. А., Волков А. Н., Мисин В. М. Кинетические характеристики взаимодействия 2,2-дифенил-1-пикрилгидразила с некоторыми природными фенольными антиоксидантами в среде этанола // звестия Академии наук. Серия химическая. - 2014. - № 9. - С. 2013-2019.

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Published

2017-05-11

Issue

Vol. 8 No. 1-2 (2016)

Section

Chemistry

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