Co-purification of water from aluminum and fluorine by the membrane from wood
DOI:
https://doi.org/10.31548/bio2018.03.013Abstract
The high efficiency of the process of water purification from Al(III) hydroxy compounds with adsorbed F−ions by a microfiltration tubular wood membrane is shown. The main regularities of this process are investigated and its technological parameters are determined.
It is established that such a high efficiency is due to the combined action of the adsorption of F−by hydroxo-compounds Al(III) and their subsequent delay by the wood membrane. At the same time, an additional selective barrier was formed on the surface of the wood membrane in the form of a self-forming dynamic membrane of Al(III) hydroxo compounds with adsorbed F− ions, which increased the efficiency of the process of water purification from them.
It is proposed to use such a membrane for joint water purification from aluminum and fluorine to the MPC of Al3+ and F− ions in water at initial concentrations of F− up to 10.0 mg/dm3 and Al3+ to 30.0 mg/dm3, pH 6.5 to 7,2, an operating pressure of 1.0 MPa and a permeate recovery rate of up to 70 %.
Keywords: wood membrane, microfiltration, F− ions, Al(III) hydroxo compounds, dynamic membrane
References
Маlаfееvа, А.V., Dоkuchаеvа, Ju.А. (2013). Sоеdinеniya ftora – zаgryaznitеli pоvеrhnоstnyh vоd zоny vliyaniya kriоlitоvоgо рrоizvоdstvа [Fluorine compounds - pollutants of surface waters of the zone of influence of cryolite production]. Proceedings of the Orenburg State Agrarian University, 4 (42), 209–211.
Shugаlеj, I.V., Gаrаbаdgiu, А.V., Ilushin, М.А., Sudаrikоv, А.М. (2012). Nеkоtоryе аspеkty vliyaniya аluminiya i еgо sоеdinеnij nа zhyvyе оrgаnizмy [Some aspects of the effect of aluminum and its compounds on living organisms]. Ecological chemistry, 21 (3), 172–186.
DSТU 7525: 2014. (2014). Vоdа pytnа. Vymоgy tа меtоdy kоntrоluvаnnya yakоsti [Water is potable. Requirements and methods of quality control]. Міnеkоnомrоzvytku Ukrаiny, 26.
Kоrzhnеv, М.М., Koshyakov, О.E. (2002). Ftоr u pytnyh vоdаh Ukrаїни ta zahvorjuvannyapov’yazanі z nimi [Fluorine in drinking water of Ukraine and diseases associated with them]. Zirkа, 354.
Каrеlin, V.А. (2012). Vоdоpоdgоtоvkа. Fizikо-himichеskiе оsnоvy prосеssоv obrabotki vody [Water treatment. Physico-chemical basis of water treatment processes]. Tomsk, Russia: Ed. Tomsk Polytechnic University, 97.
Frog, B.N., Pervov, A.G. (2014). Vodopodgotovka [Water treatment]. Мoscow., Russia: The Association construction universities, 512.
Pervov, A.G. (2009). Sovremennye vysokoeffektivnye tekhnologii ochistki vody s primeneniem membran: obratnyy osmos, nanofiltratsiya, ultrafiltratsiya [Modern highly efficient water treatment technologies using membranes: reverse osmosis, nanofiltration, ultrafiltration]. Мoscow., Russia: МGSU, 232.
Goncharuk, V.V. ed. (2011). Perspektivy razvitiya fundamentalnykh i prikladnykh issledovaniy v oblasti fiziki, khimii i biologii vody [Prospects for the development of fundamental and applied research in the field of physics, chemistry and biology of water]. Naukova dumka, 408.
Goncharuk, V.V., Kucheruk, D.D., Balakina, M.N., Dulneva, T.Yu. (2009). Ochistka vody baromembrannymi metodami na keramicheskikh membranakh [Water treatment by baromembranes methods based on ceramic membranes]. Journal of Water Chemistry and Technology, 31 (6), 396–404. https://doi.org/10.3103/S1063455X09060083
Sens, M.L., Emmendoerfer, M.L., Muller, L.C. (2015). Water filtration through wood with helical cross-flow. Desalination and Water Treatment, 53. 15–26. https://doi.org/10.1080/19443994.2013.837010
Boutilier Michael, S.H., Lee, J., Chambers, V., Venkatesh, V., Karnik, R. (2014). Water Filtration Using Plant Xylem. Plos One, 9, 1–8. : http://dx.doi.org/10.1371/journal.pone.0089934.
Dulneva, T.Yu., Titoruk, G.N., Kucheruk, D.D., Goncharuk, V.V. (2013). Ochistka stochnyh vod ot pryamyh krasiteley ultra- i nanofiltratsionnymi keramicheskimi membranami [Cleaning of waste water from direct dyes by the ultra- and nanofiltration ceramic membranes]. Journal of Water Chemistry and Technology, 35 (4), 165-169.
Svittsov, A.A. (2007). Vvedenie v membrannuyu tehnologiyu [Introduction to Membrane Technology]. Мoscow., Russia: DeLi print, 208.
GOST 4386-89. (2002). Voda pitevaya. Metod opredeleniya massovoy kontsentratsii ftoridov. [GOST 4386-89. The drinking water. Method for determining the mass concentration of fluorides]. Мoscow., Russia: Publishing house of standards, 10.
GOST 18165-89. (1990). Voda pitevaya. Metod opredeleniya massovoy kontsentratsii alyuminiya [GOST 18165-89. The drinking water. Method for determining the mass concentration of aluminum]. Мoscow., Russia: Publishing house of standards, 8.
Didyk, М.V., Kropacheva, T.N., Ermakova, М.Е. (2013). Adsorbtsiya ftorid-ionov na okside alyuminiya [Adsorption of fluoride ions on aluminum oxide]. Bulletin of the Udmurt University. Physics. Chemistry, 1, 29–34.
Kucheruk, D.D. (1991). Dinamicheskie membrany iz gidroksopolimerov alyuminiya [Dynamic membranes of aluminum hydroxocopolymers]. Journal of Water Chemistry and Technology, 13 (7), 664–669.
Pilipenko, A.T., Falendyish, N.F., Parhomenko, E.P. (1982). Sostoyanie alyuminiya v vodnyih rastvorah [The state of aluminum in aqueous solutions]. Journal of Water Chemistry and Technology, 4 (2), 135–150.
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