Heavy metals in soil: mobility as a criterion of environmental hazard
DOI:
https://doi.org/10.31548/biologiya2019.02.044Abstract
The article presents results of researchthe relationship between mobility of heavy metals and soil parameters for the subsequent forecast their environmental hazard.For the characteristics of mobile formsofheavymetalsinthesoilusedcomplexextractantstransportationgrossstockofheavy metals in soils were taken away by a mixture of H2SO4+HF, potentially mobile form -1, 0 N HCL, mobile- 0,1N HCL. Examinedthesoil, characteristicforzonesofPolissya, Forest-steppeandSteppeUkraine.
Itwasfoundthatonthebackgroundofincreasingthecontentofgrossformsofheavymetalsfrompodzolsoilstochernozemsmollic, theircontentsinmobileformsinthefuture. Theshareofmobileformsofmetals (m+ n) inthepodzolsoilranged 29.0-62.5 %, chernozemsmollic – 2.8-21.9 %.
Selected characteristics of the soil, the mobility of heavy metals contents of clay minerals (the < 0.001 mm), thecontentoforganicmatterinthesoil, soilpH.Dose inverse correlation was observed between the contents of clay minerals and the contents of mobile forms of heavy metals in the soil, r ranged from (-) 0.643 (-) 0.962.
It was shown that the actual danger of heavy metals you need to evaluate the contents of mobile forms, extract with 0.1 N acids, the potential is 1.0 N acids. Prediction of danger of heavy metals must take into account the parameters of soils: physical clay, organic matter and Ph.
Keywords: heavy metals, soil, mobility, environmental safety.
References
Domergue F.-L.Mobility of Heavy Metals in Soil Profiles [Text] / F.-L. Domergue,J.-C. Védy //International Journal of Environmental Analytical Chemistry. - Volume 46, 1992 - Issue 1-3. Published online: 23 Sep 2006. https://doi.org/10.1080/03067319208026993
Khaled S.Field accumulation risks of heavy metals in soil and vegetable crop irrigated with sewage water in western region of Saudi Arabia [Text] / Khaled S., BalkhairMuhammad Aqeel Ashraf //Saudi Journal of Biological Sciences. - Volume 23, Issue 1, Supplement, January 2016. - Pages S32-S44. https://doi.org/10.1016/j.sjbs.2015.09.023
KrzysztofFijalkowski, MalgorzataKacprzak, AnnaGrobelak, AgnieszkaPlacek. The influence of selected soil parameters on the mobility of heavy metals in soil. InżynieriaiOchronaŚrodowiska. 2012, t. 15, nr 1, s. 81-92. https://www.researchgate.net/publication/282734701
OECDTestGuidelinesfortheChemicals (2019). OECDGuidelinesfortheTestingofChemicals, Section 3. https://doi.org/10.1787/2074577x
Ogundiran M. B. Mobility and speciation of heavy metals in soils impacted by hazardous waste [Text]/ M. B. Ogundiran, O. Osibanjo //Chemical Speciation & Bioavailability. - Volume 21, 2009 - Issue 2. https://doi.org/10.3184/095422909X449481
Sungur Ali. Characterization of Heavy Metal Fractions in Agricultural Soils by Sequential Extraction Procedure: The Relationship Between Soil Properties and Heavy Metal Fractions [Text] / Ali Sungur, Mustafa Soylak, Erkan Yilmaz, Selehattin Yilmaz, Hasan Ozcan //Soil and Sediment Contamination: An International Journal. - Volume 24, 2015 - Issue 1 . https://doi.org/10.1080/15320383.2014.907238
Sungur Ali. Investigation of heavy metal mobility and availability by the BCR sequential extraction procedure: relationship between soil properties and heavy metals availability [Text]/ Ali Sungur, Mustafa Soylak, Hasan Ozcan // Chemical Speciation & Bioavailability. - Volume 26, 2014 - Issue 4. https://doi.org/10.3184/095422914X14147781158674
Tóth G. Heavy metals in agricultural soils of the European Union with implications for food safety [Text] / G.TóthT.HermannM.R.Da SilvaL. Montanarella //Environment International. – 2016. - Volume 88 - Pages 299-309. https://doi.org/10.1016/j.envint.2015.12.017
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