MICROPOROUS CARBONATE CATALYSTS FROM LIGNOCELLULAR WASTE PROCESSING SORGO (BAGASSE)

Authors

  • L. A. Kupchyk Institute Of Sorption And Problems Of Endoecology Of Nas Of Ukraine , Інститут сорбції та проблеми ендоекології НАС України
  • L. Y. Kotynska Institute Of Sorption And Problems Of Endoecology Of Nas Of Ukraine , Інститут сорбції та проблеми ендоекології НАС України
  • N. V. Sych Institute Of Sorption And Problems Of Endoecology Of Nas Of Ukraine , Інститут сорбції та проблеми ендоекології НАС України
  • N. A. Grigorenko Institute Of Food Resources Of The National Academy Of Sciences Of Ukraine , Інститут харчових ресурсів Національної академії наук України

DOI:

https://doi.org/10.31548/dopovidi2017.06.016

Keywords:

bagasse, structural-sorption properties, catalyst, hydrolysis, sucrose

Abstract

New microporous carbon materials from lignocellulosic sorghum waste (bagasse) were synthesized and their structural-porous and ion-exchange characteristics were studied. A method of thermochemical modification of the surface of synthesized coals is proposed to improve the sorption and catalytic ability. The activity of the obtained carbon catalysts in the process of hydrolytic splitting of sucrose was studied.
 

References

Strelko, V. V. (2007). Selective sorption and catalysis on active coals and inorganic ion exchangers. Kyiv, Ukraine: Naukova Dumka, 205.

Kupchik, L. A, Nikolaychuk, A. A., Cartel, N. T., Denisovich, V. A. (2006). Synthesis and properties of biosorbents obtained on the basis of cellulose-lignin plant material - wastes of the agro-industrial complex. Sorption and chromatographic processes, 7 (3), 489-498.

Kupchik, L. A., Gololob, E. Yu., Korostyatynets, V. D., Kartel, N.T. (2000). Prospects of use of polysaccharide-containing natural materials for the creation of adsorptive means. Sorption Methods and Technologies in the Settlement of Ecological and Endoecological Problems of the Chernobyl Accident, 30.

Nikolaychuk, A. A. (2005). Synthesis of the power of biosorbents on the basis of cellulose and lignin in sislini. The scientific notes of NAUKMA. Chemical Sciences of Technologies, 42, 28-31.

Mikhalovsky, S. V., Nikolaev, V. G. (2006). Activated carbon surfaces in environmental remediation. Amsterdam: Academic Press, 529-561.

https://doi.org/10.1016/S1573-4285(06)80020-7

Ion exchangers: Methods for determining exchange capacity. (1989). GOST 20255.1-89. Moscow, USSR.

Gregg, S. J., Sing, K. S. W. (1982). Adsorption, Surface Area and Porosity. 2nd ed. London, New York, Paris, San Diego, San Francisco, San Paulo, Sydney, Tokyo, Toronto: Academic Press, 303.

Stavitskaya, S. S. (2004). Acid-base properties of carbon adsorbents, determined by the potentiometric titration method. ZhHKh, 77 (8), 1279-1283.

https://doi.org/10.1007/s11167-005-0011-y

Zaitsev, Y., Stavitskaya, S., Zhuravsky, S., Strelko, V. (2004). Catalytic oxidation of hydrogen sulfide by molecular oxygen on N-contained activated carbons. International Conference Carbon for catalysis "CarboCat-04". Kyiv (Ukraine), 51-57.

Tarkovskaya, I. A. (1981). Oxidized coal. Kyiv: Naukova Dumka, 328.

Strelko, V. V., Stavitsrkaya, S. S., Gorlov, Yu. I. (2014). Proton catalysis with active carbons and partially pyrolyzed carbonaceous materials. Chine Journal of Catalysis, 35, 815-823.

https://doi.org/10.1016/S1872-2067(14)60147-9

Mikhalovsky, S. V., Nikolaev, V. G. (2006). Activated carbon surfaces in environmental remediation. Amsterdam: Academic Press, 529-561.

https://doi.org/10.1016/S1573-4285(06)80020-7

Danilenko, V. S., Nosenko, V. M., Zabarsky, O. M. (2002). A new adsorbent preparation - activated carbon "KM". New medicinal preparations. Express information, 2, 487 - 491.

Baranov, S. N., Saranchuk, V. I., Sapunov, V. A. (1983). Chemical products from coal. Kiev: Naukova dumka, 116.

Methods for determination of reducing substances. (2001). GOST 12575-2001 from 1st January 2003. Russia.

Chesnokov, N. V., Yatsenkov, O. V. (2012). The study of the reaction of acid-catalytic hydrolysis of sucrose. Journal of Siberian Federal University. Chemistry, 3 (5), 311-319.

Zajseck, K., Grizec, A. (2010). A kinetic studu of sucrose hydrolysis over Amberlite IR-120 as a heterogeneous catalyst using in situ FTIR shectroscopy. React. Kinet. Mech. Cat., 100, 265-276 .

https://doi.org/10.1007/s11144-010-0154-6

Published

2017-12-30

Issue

Section

Machinery & Automation ofAgriculture 4.0